"Alkynoates" Example Sentences
1. Alkynoates have unique chemical properties that distinguish them from other carboxylate compounds.
2. The synthesis of alkynoates requires careful consideration of reaction conditions and reagents.
3. The reaction of alkynoates with halogens can lead to the formation of haloalkynoates.
4. Alkynoates can undergo addition reactions with nucleophiles, such as water or alcohol.
5. The stability of alkynoates depends on the substitution pattern of the alkyne and carboxylate groups.
6. Alkynoates are versatile building blocks for the synthesis of complex organic molecules.
7. The addition of alkynoates to dienophiles can lead to the formation of highly substituted cyclohexenes.
8. The electrophilic addition of elements like boron or silicon to alkynoates can create new functional groups.
9. The regioselectivity of the alkyne in alkynoates can be influenced by the choice of catalyst or solvent.
10. The use of alkynoates in click chemistry has enabled the rapid synthesis of diverse chemical libraries.
11. The presence of functional groups in alkynoates can dictate their reactivity and suitability for different reactions.
12. The conversion of alkynoates to enolates can enable them to act as nucleophiles in different reactions.
13. The reaction of alkynoates with aldehydes or ketones can lead to the formation of α,β-unsaturated carbonyl compounds.
14. The modification of the alkyne moiety in alkynoates can lead to changes in their stereochemistry or reactivity.
15. The reactivity of alkynoates can be modulated through the use of different metal catalysts.
16. The arylation of alkynoates can facilitate the introduction of aryl groups into organic compounds.
17. The esterification of alkynoates can be used to enhance their solubility or stability.
18. The substitution of alkynoates can be influenced by factors such as steric hindrance or resonance stabilization.
19. The use of chiral alkynoates can enable the synthesis of enantiopure organic molecules.
20. The generation of alkynoates from alkynes and carboxylic acids can require the use of acidic or basic catalysts.
21. The reaction of alkynoates with nitro compounds can lead to the formation of nitroalkenes.
22. The deprotection of alkynoates can be achieved through the use of different reagents or conditions.
23. The combination of alkynoates with other building blocks, such as halides or alkenes, can lead to the formation of complex chemical structures.
24. The reduction of alkynoates can lead to the formation of alcohols or alkanes, depending on the reagents and reaction conditions.
25. The application of alkynoates in bioconjugation can facilitate the labeling of biological molecules with fluorescent or radioactive probes.
26. The selectivity of alkynoates in different reactions can be influenced by the use of protecting groups or templates.
27. The reaction of alkynoates with isocyanates can lead to the formation of urethanes or isocyanurates.
28. The use of alkynoates as ligands in metal catalysts can facilitate the formation of complex organic molecules.
29. The conversion of alkynoates to nitriles can be achieved through the use of different reagents, such as copper(I) cyanide.
30. The reaction of alkynoates with heterocyclic compounds can lead to the formation of substituted furans or pyrroles.
31. The formation of alkynoates from 1,1-dibromoalkanes and silver alkynylides can provide access to different organic frameworks.
32. The reaction of alkynoates with nitrous acid can lead to the formation of diazo compounds.
33. The halogenation of alkynoates can be used to introduce functional groups or create valuable synthetic intermediates.
34. The application of alkynoates in materials chemistry can facilitate the design of new polymers or supramolecular assemblies.
35. The use of alkynoates in the synthesis of natural products can provide access to diverse structural motifs.
36. The oxidation of alkynoates can be achieved through the use of different oxidants, such as potassium permanganate or Jones reagent.
37. The reaction of alkynoates with acyl chlorides can facilitate the formation of β-ketoalkynates.
38. The dehydrogenation of alkynoates can lead to the formation of conjugated alkynes or alkadienes.
39. The use of alkynoates in name reactions, such as the Pauson-Khand reaction or the Hendrickson-Brook rearrangement, can provide access to important organic compounds.
40. The diversity and versatility of alkynoates make them valuable tools for organic synthesis and chemical biology.
Common Phases
1.
Alkynoates are versatile compounds;
2.
Alkynoates can be synthesized using various methods;
3.
Alkynoates have unique reactivity due to their triple bond;
4.
Alkynoates are used in pharmaceutical and agrochemical industries;
5.
Alkynoates can be used as ligands in transition metal catalysis;
6.
Alkynoates are used in organic synthesis as building blocks for complex molecules.